posted on 2025-08-06, 15:44authored byE-M Ahrer, KB Stevenson, M Mansfield, SE Moran, J Brande, J Morello, CA Murray, NK Nikolov, JDM Petit dit de la Roche, E Schlawin, PJ Wheatley, S Zieba, NE Batalha, M Damiano, JM Goyal, M Lendl, JD Lothringer, S Mukherjee, K Ohno, NM Batalha, MP Battley, TG Beatty, B Benneke, ZK Berta-Thompson, AL Carter, PE Cubillos, T Daylan, N Espinoza, P Gao, NP Gibson, S Gill, J Harrington, R Hu, L Kreidberg, NK Lewis, MR Line, M López-Morales, V Parmentier, DK Powell, DK Sing, S-M Tsai, SR Wakeford, L Welbanks, MK Alam, L Alderson, NH Allen, DR Anderson, JK Barstow, D Bayliss, TJ Bell, J Blecic, EM Bryant, MR Burleigh, L Carone, SL Casewell, Q Changeat, KL Chubb, IJM Crossfield, M Crouzet, L Decin, J-M Désert, AD Feinstein, L Flagg, JJ Fortney, JE Gizis, K Heng, N Iro, E M-R Kempton, S Kendrew, J Kirk, HA Knutson, TD Komacek, P-O Lagage, J Leconte, J Lustig-Yaeger, RJ MacDonald, L Mancini, EM May, NJ Mayne, Y Miguel, T Mikal-Evans, K Molaverdikhani, E Palle, C Piaulet, BV Rackham, S Redfield, LK Rogers, P-A Roy, Z Rustamkulov, EL Shkolnik, KS Sotzen, J Taylor, P Tremblin, GS Tucker, JD Turner, M de Val-Borro, O Venot, X Zhang
Measuring the metallicity and carbon-to-oxygen (C/O) ratio in exoplanet atmospheres is
a fundamental step towards constraining the dominant chemical processes at work and,
if in equilibrium, revealing planet formation histories. Transmission spectroscopy
provides the necessary means by constraining the abundances of oxygen- and
carbon-bearing species; however, this requires broad wavelength coverage, moderate
spectral resolution, and high precision that, together, are not achievable with previous
observatories. Now that JWST has commenced science operations, we are able to
observe exoplanets at previously uncharted wavelengths and spectral resolutions. Here
we report time-series observations of the transiting exoplanet WASP-39b using JWST’s
Near InfraRed Camera (NIRCam). The long-wavelength spectroscopic and
short-wavelength photometric light curves span 2.0 – 4.0 µm, exhibit minimal
systematics, and reveal well-defined molecular absorption features in the planet’s
spectrum. Specifically, we detect gaseous H O in the atmosphere and place an upper
limit on the abundance of CH . The otherwise prominent CO feature at 2.8 µm is
largely masked by H O. The best-fit chemical equilibrium models favour an
atmospheric metallicity of 1–100× solar (i.e., an enrichment of elements heavier than
helium relative to the Sun) and a sub-stellar carbon-to-oxygen (C/O) ratio. The inferred
high metallicity and low C/O ratio may indicate significant accretion of solid materials
during planet formation or disequilibrium processes in the upper atmosphere.
This version is made available under the CC-BY 4.0 license: https://creativecommons.org/licenses/by/4.0/
Submission date
2022-10-20
Notes
This is the author accepted manuscript. the final version is available from Nature Research via the DOI in this record
Data Availability: The data used in this paper are associated with JWST program ERS 1366 (observation #2)
and are available from the Mikulski Archive for Space Telescopes (https://mast.stsci.edu). We
used calibration data from program 1076. All the data and models presented in this
publication can be found at https://doi.10.5281/zenodo.7101283.
Code Availability: The codes used in this publication to extract, reduce and analyse the data are as follows:
Batman, emcee, Eureka!, jwst, chromatic, chromatic-fitting, PyMC359, Exoplanet, gCMCRT, CONAN, ExoTiC-LD, LACOSMIC, PICASO, Virga, VULCAN