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Quantum work statistics close to equilibrium

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posted on 2025-08-01, 11:17 authored by M Scandi, HJD Miller, J Anders, M Perarnau-Llobet
We study the statistics of work, dissipation, and entropy production of a quantum quasi-isothermal process, where the system remains close to thermal equilibrium along the transformation. We derive a general analytic expression for the work distribution and the cumulant generating function. All work cumulants split into classical (noncoherent) and quantum (coherent) terms, implying that close to equilibrium there are two independent channels of dissipation at all levels of the statistics. For noncoherent or commuting protocols, only the first two cumulants survive, leading to a Gaussian distribution with its first two moments related through the classical fluctuation-dissipation relation. On the other hand, quantum coherence leads to positive skewness and excess kurtosis in the distribution, and we demonstrate that these non-Gaussian effects are a manifestation of asymmetry in relation to the resource theory of thermodynamics. Furthermore, we also show that the noncoherent and coherent contributions to dissipation satisfy independently the Evans-Searles fluctuation theorem, which sets strong bounds on the fluctuations in dissipation, with negative values exponentially suppressed. Our findings are illustrated in a driven two-level system and an Ising chain, where quantum signatures of the work distribution in the macroscopic limit are discussed.

Funding

713729

EP/R045577/1

Engineering and Physical Sciences Research Council (EPSRC)

European Union Horizon 2020

Fundacio Cellex, Generalitat de Catalunya

PZOOP2_186067/1

QIBEQI FIS2016-80773-P

Royal Society

SGR 1381

Severo Ochoa SEV-2015-0522

Spanish MINECO

Swiss National Science Foundation

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© 2020. Open access. Published by the American Physical Society under the terms of the Creative Commons Attribution 4.0 International license. Further distribution of this work must maintain attribution to the author(s) and the published article's title, journal citation, and DOI. Open access publication funded by the Max Planck Society.

Notes

This is the final version. Available on open access from the American Physical Society via the DOI in this record

Journal

Physical Review Research

Publisher

American Physical Society (APS)

Version

  • Version of Record

Language

en

FCD date

2020-12-28T10:06:31Z

FOA date

2021-01-04T07:25:19Z

Citation

Vol. 2 (2), article 023377

Department

  • Physics and Astronomy

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