Experimental and DFT Insights on Microflower g-C3N4/BiVO4 Photocatalyst for Enhanced Photoelectrochemical Hydrogen Generation from Lake water
Samsudin, MFR; Ullah, H; Bashiri, R; et al.Mohamed, NM; Sufian, S; Ng, YH
Date: 8 June 2020
Journal
ACS Sustainable Chemistry & Engineering
Publisher
American Chemical Society (ACS)
Publisher DOI
Abstract
Herein, an experimental and Density Functional Theory (DFT) analysis of the composite g-C3N4/BiVO4 microflower photocatalysts were comprehensively discussed. A remarkable photoelectrocatalytic solar hydrogen production has been observed for the as-developed photocatalysts, with different loading amounts of g-C3N4 (0.1, 0.4, 0.8, and ...
Herein, an experimental and Density Functional Theory (DFT) analysis of the composite g-C3N4/BiVO4 microflower photocatalysts were comprehensively discussed. A remarkable photoelectrocatalytic solar hydrogen production has been observed for the as-developed photocatalysts, with different loading amounts of g-C3N4 (0.1, 0.4, 0.8, and 1.2 wt.%), using lake water without the addition of sacrificial reagents. The 0.8 wt.% g-C3N4/BiVO4 microflower photocatalyst evinced remarkable photoelectrocatalytic activity of 21.4 mmol/h of hydrogen generated in comparison to other samples with an AQE of 4.27% at 420 nm. In addition, the photocurrent density of 0.8 wt.% g-C3N4/BiVO4 microflower was two-fold higher than that of pure BiVO4. This was attributed to its better crystallinity and optical properties; confirmed from XRD and DR-UV-Vis analysis. The DFT analysis further corroborated that the efficient photocharge carrier separation and limited photocharge carrier recombination corresponded to the synergistic effect of the band offset and built-in electric field.
Engineering
Faculty of Environment, Science and Economy
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