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dc.contributor.authorByrne, P
dc.contributor.authorHudson-Edwards, K
dc.contributor.authorBird, G
dc.contributor.authorMacklin, MG
dc.contributor.authorBrewer, PA
dc.contributor.authorWilliams, RD
dc.contributor.authorJamieson, HE
dc.date.accessioned2018-02-05T12:19:36Z
dc.date.issued2018-01-31
dc.description.abstractThe Mount Polley mine tailings embankment breach on August 4th, 2014, in British Columbia, Canada, is the second largest mine waste spill on record. The mine operator responded swiftly by removing significant quantities of tailings from the primary receiving watercourse, stabilizing the river corridor and beginning construction of a new river channel. This presented a unique opportunity to study spatial patterns of element cycling in a partially-restored and alkaline river system. Overall, water quality impacts are considered low with Cu, and to a lesser extent V, being the only elements of concern. However, the spatial pattern of stream Cu loading suggested chemical (dominant at low flow) and physical (dominant at high flow) mobilization processes operating in different parts of the watershed. Chemical mobilization was hypothesized to be due to Cu sulfide (chalcopyrite) oxidation in riparian tailings and reductive dissolution of Cu-bearing Fe oxides in tailings and streambed sediments whereas physical mobilization was due to erosion and suspension of Cu-rich stream sediments further downstream. Although elevated aqueous Cu was evident in Hazeltine Creek, this is considered a relatively minor perturbation to a watershed with naturally elevated stream Cu concentrations. The alkaline nature of the tailings and the receiving watercourse ensures most aqueous Cu is rapidly complexed with dissolved organic matter or precipitates as secondary mineral phases. Our data highlights how swift removal of spilled tailings and river corridor stabilization can limit chemical impacts in affected watersheds but also how chemical mobilization (of Cu) can still occur when the spilled tailings and the receiving environment are alkaline. We present a conceptual model of Cu cycling in the Hazeltine Creek watersheden_GB
dc.description.sponsorshipThis work was funded by the UK Natural Environment Research Council (grant NE/M017486/1). We thank Lyn Anglin, Colleen Hughes and Art Frye of Mount Polley Mining Corporation for facilitating site access, providing site information and data, and for field support. We also thank Phil Riby (Liverpool John Moores University) for ICP-MS analytical support and Agen_GB
dc.identifier.citationVol. 91, pp. 64 - 74en_GB
dc.identifier.doi10.1016/j.apgeochem.2018.01.012
dc.identifier.urihttp://hdl.handle.net/10871/31321
dc.language.isoenen_GB
dc.publisherElsevieren_GB
dc.relation.sourceSupplementary data related to this article can be found at http://dx. doi.org/10.1016/j.apgeochem.2018.01.012.en_GB
dc.rights© 2018 The Authors. Published by Elsevier Ltd. This is an open access article under the CC BY license (http://creativecommons.org/licenses/BY/4.0/)en_GB
dc.subjectMount Polleyen_GB
dc.subjectMine wasteen_GB
dc.subjectTailingsen_GB
dc.subjectRiver restorationen_GB
dc.subjectWater qualityen_GB
dc.subjectCopperen_GB
dc.titleWater quality impacts and river system recovery following the 2014 Mount Polley mine tailings dam spill, British Columbia, Canadaen_GB
dc.typeArticleen_GB
dc.date.available2018-02-05T12:19:36Z
dc.identifier.issn0883-2927
dc.descriptionThis is the final version of the article. Available from the publisher via the DOI in this record.en_GB
dc.identifier.journalApplied Geochemistryen_GB


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