Simple, yet versatile, methods to functionalize graphene flakes with metal (oxide) nanoparticles
are in demand, particularly for the development of advanced catalysts. Herein, we report a laserassisted, continuous, solution route for the simultaneous reduction and modification of
graphene oxide with catalytic nanoparticles. Electrochemical ...
Simple, yet versatile, methods to functionalize graphene flakes with metal (oxide) nanoparticles
are in demand, particularly for the development of advanced catalysts. Herein, we report a laserassisted, continuous, solution route for the simultaneous reduction and modification of
graphene oxide with catalytic nanoparticles. Electrochemical graphene oxide (EGO) was used
as both the starting material and electron-hole pair source due to its low degree of oxidation,
which imparts structural integrity and an ability to withstand photo-degradation. Simply
illuminating a stream containing EGO and metal salt precursor solutions(e.g. H2PtCl6 or RuCl3)
with a 248 nm wavelength laser produced reduced EGO (rEGO, oxygen content 4.0 at.%) flakes
decorated with Pt (~2.0 nm) or RuO2 (~2.8 nm) nanoparticles. The RuO2-rEGO flakes exhibited
superior catalytic activity for the oxygen evolution reaction, requiring a small overpotential of
225 mV to reach a current density of 10 mA cm−2
. Whereas, the Pt-rEGO flakes shows
significantly enhanced mass activity for the hydrogen evolution reaction and a similar
performance for oxygen reduction reaction compared to a commercial 20% Pt/C catalyst. This
simple production method was also used to deposit PtPd alloy and MnOx nanoparticles on
rEGO , demonstrating its versatility in synthesizing functional nanoparticle-modified graphene
materials.