Laser Assisted Solution Synthesis of High Performance Graphene Supported Electrocatalysts
dc.contributor.author | Peng, Y | |
dc.contributor.author | Cao, J | |
dc.contributor.author | Yang, J | |
dc.contributor.author | Yang, W | |
dc.contributor.author | Zhang, C | |
dc.contributor.author | Li, X | |
dc.contributor.author | Dryfe, RAW | |
dc.contributor.author | Li, L | |
dc.contributor.author | Kinloch, IA | |
dc.contributor.author | Liu, Z | |
dc.date.accessioned | 2020-05-05T12:34:52Z | |
dc.date.issued | 2020-06-25 | |
dc.description.abstract | Simple, yet versatile, methods to functionalize graphene flakes with metal (oxide) nanoparticles are in demand, particularly for the development of advanced catalysts. Herein, we report a laserassisted, continuous, solution route for the simultaneous reduction and modification of graphene oxide with catalytic nanoparticles. Electrochemical graphene oxide (EGO) was used as both the starting material and electron-hole pair source due to its low degree of oxidation, which imparts structural integrity and an ability to withstand photo-degradation. Simply illuminating a stream containing EGO and metal salt precursor solutions(e.g. H2PtCl6 or RuCl3) with a 248 nm wavelength laser produced reduced EGO (rEGO, oxygen content 4.0 at.%) flakes decorated with Pt (~2.0 nm) or RuO2 (~2.8 nm) nanoparticles. The RuO2-rEGO flakes exhibited superior catalytic activity for the oxygen evolution reaction, requiring a small overpotential of 225 mV to reach a current density of 10 mA cm−2 . Whereas, the Pt-rEGO flakes shows significantly enhanced mass activity for the hydrogen evolution reaction and a similar performance for oxygen reduction reaction compared to a commercial 20% Pt/C catalyst. This simple production method was also used to deposit PtPd alloy and MnOx nanoparticles on rEGO , demonstrating its versatility in synthesizing functional nanoparticle-modified graphene materials. | en_GB |
dc.description.sponsorship | University of Manchester | en_GB |
dc.description.sponsorship | Engineering and Physical Sciences Research Council (EPSRC) | en_GB |
dc.description.sponsorship | European Union Horizon 2020 | en_GB |
dc.identifier.citation | Published online 25 June 2020 | en_GB |
dc.identifier.doi | 10.1002/adfm.202001756 | |
dc.identifier.grantnumber | EP/N032888/1 | en_GB |
dc.identifier.grantnumber | 785219 | en_GB |
dc.identifier.uri | http://hdl.handle.net/10871/120929 | |
dc.language.iso | en | en_GB |
dc.publisher | Wiley | en_GB |
dc.rights | © 2020 The Authors. Published by WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim. This is an open access article under the terms of the Creative Commons Attribution License, which permits use, distribution and reproduction in any medium, provided the original work is properly cited. | |
dc.subject | laser | en_GB |
dc.subject | graphene oxide | en_GB |
dc.subject | nanoparticles | en_GB |
dc.subject | electrocatalysts | en_GB |
dc.title | Laser Assisted Solution Synthesis of High Performance Graphene Supported Electrocatalysts | en_GB |
dc.type | Article | en_GB |
dc.date.available | 2020-05-05T12:34:52Z | |
dc.identifier.issn | 1616-301X | |
dc.description | This is the final version. Available on open access from Wiley via the DOI in this record | en_GB |
dc.identifier.journal | Advanced Functional Materials | en_GB |
dc.rights.uri | https://creativecommons.org/licenses/by/4.0/ | en_GB |
dcterms.dateAccepted | 2020-05-04 | |
rioxxterms.version | VoR | en_GB |
rioxxterms.licenseref.startdate | 2020-05-04 | |
rioxxterms.type | Journal Article/Review | en_GB |
refterms.dateFCD | 2020-05-04T17:57:18Z | |
refterms.versionFCD | AM | |
refterms.dateFOA | 2020-06-29T09:21:24Z | |
refterms.panel | B | en_GB |
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Except where otherwise noted, this item's licence is described as © 2020 The Authors. Published by WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim.
This is an open access article under the terms of the Creative Commons Attribution License, which permits use, distribution and reproduction in any medium, provided the original work is properly cited.