In systems of more than two reactive radicals, the radical recombination probability can be magnetosensitive due to the mere effect of the inter-radical electron-electron dipolar coupling. Here, we demonstrate that this principle, previously established for three-radical systems, generalizes to n-radical systems. We focus on radical ...
In systems of more than two reactive radicals, the radical recombination probability can be magnetosensitive due to the mere effect of the inter-radical electron-electron dipolar coupling. Here, we demonstrate that this principle, previously established for three-radical systems, generalizes to n-radical systems. We focus on radical systems in the plane and explore the effects of symmetry, in particular its absence, on the associated magnetic field effects of the recombination yield. We show, by considering regular configurations and slightly distorted geometries, that the breaking of geometric symmetry can lead to an enhancement of the magnetosensitivity of these structures. Furthermore, we demonstrate the presence of effects at low-field that are abolished in the highly symmetric case. This could be important to the understanding of the behavior of radicals in biological environments in the presence of weak magnetic fields comparable to the Earth's, as well as the construction of high-precision quantum sensing devices.