Molecular strong coupling and cavity finesse (article)
dc.contributor.author | Menghrajani, KS | |
dc.contributor.author | Vasista, AB | |
dc.contributor.author | Tan, WJ | |
dc.contributor.author | Thomas, PA | |
dc.contributor.author | Herrera, F | |
dc.contributor.author | Barnes, WL | |
dc.date.accessioned | 2024-07-25T12:47:34Z | |
dc.date.issued | 2024-07-15 | |
dc.date.updated | 2024-07-03T10:26:54Z | |
dc.description.abstract | Molecular strong coupling offers exciting prospects in physics, chemistry and materials science. Whilst attention has been focused on developing realistic models for the molecular systems, the important role played by the entire photonic mode structure of the optical cavities has been less explored. We show that the effectiveness of molecular strong coupling may be critically dependent on cavity finesse. Specifically we only see emission associated with a dispersive lower polariton for cavities with sufficient finesse. By developing an analytical model of cavity photoluminescence in a multimode structure we clarify the role of finite-finesse in polariton formation, and show that lowering the finesse reduces the extent of the mixing of light and matter in polariton states. We suggest that the detailed nature of the photonic modes supported by a cavity will be as important in developing a coherent framework for molecular strong coupling as the inclusion of realistic molecular models. | en_GB |
dc.description.sponsorship | Leverhulme Trust | en_GB |
dc.description.sponsorship | Royal Society | en_GB |
dc.description.sponsorship | European Research Council (ERC) | en_GB |
dc.description.sponsorship | Fondecyt | en_GB |
dc.description.sponsorship | Millennium Science Initiative | en_GB |
dc.identifier.citation | Vol. 15 (29), pp. 7449–7457 | en_GB |
dc.identifier.doi | https://doi.org/10.1021/acs.jpclett.4c00782 | |
dc.identifier.grantnumber | 119893R | en_GB |
dc.identifier.grantnumber | ERC-2016-AdG-742222 | en_GB |
dc.identifier.grantnumber | 1221420 | en_GB |
dc.identifier.grantnumber | ICN17_012 | en_GB |
dc.identifier.uri | http://hdl.handle.net/10871/136885 | |
dc.identifier | ORCID: 0000-0002-9474-5534 (Barnes, William) | |
dc.language.iso | en | en_GB |
dc.publisher | American Chemical Society | en_GB |
dc.relation.url | https://doi.org/10.24378/exe.5306 | en_GB |
dc.rights | © 2024 The Authors. Published by American Chemical Society. Open access. This publication is licensed under CC-BY 4.0 | en_GB |
dc.subject | Absorption | en_GB |
dc.subject | Cavities | en_GB |
dc.subject | Energy | en_GB |
dc.subject | Polaritons | en_GB |
dc.subject | Quantum Mechanics | en_GB |
dc.title | Molecular strong coupling and cavity finesse (article) | en_GB |
dc.type | Article | en_GB |
dc.date.available | 2024-07-25T12:47:34Z | |
dc.identifier.issn | 1948-7185 | |
dc.description | This is the final version. Available on open access from the American Chemical Society via the DOI in this record | en_GB |
dc.description | The dataset associated with this article is available in ORE at https://doi.org/10.24378/exe.5306 | en_GB |
dc.identifier.eissn | 1948-7185 | |
dc.identifier.journal | Journal of Physical Chemistry Letters | en_GB |
dc.relation.ispartof | Journal of Physical Chemistry Letters | |
dc.rights.uri | https://creativecommons.org/licenses/by/4.0/ | en_GB |
dcterms.dateAccepted | 2024-06-28 | |
dcterms.dateSubmitted | 2024-03-13 | |
rioxxterms.version | VoR | en_GB |
rioxxterms.licenseref.startdate | 2024-06-28 | |
rioxxterms.type | Journal Article/Review | en_GB |
refterms.dateFCD | 2024-07-03T10:26:58Z | |
refterms.versionFCD | P | |
refterms.dateFOA | 2024-07-25T12:48:11Z | |
refterms.panel | B | en_GB |
exeter.rights-retention-statement | Yes |
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Except where otherwise noted, this item's licence is described as © 2024 The Authors. Published by American Chemical Society. Open access. This publication is licensed under CC-BY 4.0