Evolution of thermal properties from graphene to graphite

Abstract

We report on the evolution of thermal properties from graphene to graphite as a function of layer thickness and temperature. The onset of the inter-layer compressional elastic constant C33 and the shear elastic constant C44 results in a large difference between the magnitudes and temperature dependencies of the specific heat and in-plane lattice thermal conductivity of bi-layer graphene (BLG) and single-layer graphene. The changes between BLG and few-layer graphene (FLG) decrease with increase in the number of layers. The cross-plane lattice thermal conductivity increases almost linearly with the number of layers in ultra-thin FLG. © 2014 AIP Publishing LLC.